Calorimetry Heat Transfer Calculator

In an insulated calorimeter, heat lost by the hot body equals heat gained by the cold one. The final temperature is the heat-capacity-weighted average of the starting temperatures.

Also called: Equilibrium temperature calculator · Mixing temperature calculator

  • Last updated
  • Formula tested against reference values

Your numbers

Aluminium 897, copper 385, iron about 450, water 4184.

Optional. The cup starts at the water’s temperature. Leave blank for an ideal, weightless cup.

Result

Final (equilibrium) temperature
—°C

Calculating…

Heat transferred from the hot object
—
Temperature change of the hot object
—
Temperature change of the water
—

How to use this calculator

  1. Enter or choose mass of the hot object.
  2. Enter or choose specific heat of the hot object.
  3. Enter or choose starting temperature of the hot object.
  4. Enter or choose mass of the water (second body).
  5. Enter or choose specific heat of the water (second body).
  6. The final (equilibrium) temperature updates as you type. Use Copy result or Share to keep it.

Method

T_f = (m₁c₁T₁ + (m₂c₂ + C_cal)T₂) ÷ (m₁c₁ + m₂c₂ + C_cal); Q = m₁c₁(T₁ − T_f)

m₁, c₁, T₁
mass, specific heat and starting temperature of the hot object
m₂, c₂, T₂
the same for the water or second body
C_cal
heat capacity of the calorimeter cup

Worked example

  1. m₁c₁ = 0.5 × 897 = 448.5 J/K; m₂c₂ = 1 × 4184 = 4184 J/K.
  2. T_f = (448.5 × 100 + 4184 × 20) ÷ (448.5 + 4184) = 128 530 ÷ 4632.5 = 27.745 °C.
  3. Q = 448.5 × (100 − 27.745) = 32 406 J = 32.41 kJ.

A 0.5 kg block of aluminium at 100 °C dropped into 1 kg of water at 20 °C brings both to about 27.7 °C, transferring 32.4 kJ.

What the result means

Water’s large specific heat means it changes temperature much less than the metal. Measure T_f in the lab and you can solve the same balance backwards for an unknown specific heat.

Assumptions and limits

  • The system is insulated: no heat is lost to the surroundings.
  • No phase change or chemical reaction occurs.
  • Specific heats are constant.
  • If the result is above 100 °C or below 0 °C for water, a phase change would occur and this result is not valid.

Questions

What is the calorimeter constant?

The heat capacity of the cup, stirrer and thermometer in J/K. It is found by mixing known masses of hot and cold water and is added to the cold side.

Why is the heat released positive?

It is measured from the hot object’s point of view: it loses that much energy, and the water gains the same amount.